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ChemInform Abstract: Enantioselective Allylation, Crotylation, and Reverse Prenylation of Substituted Isatins: Iridium-Catalyzed C—C Bond-Forming Transfer Hydrogenation.

✍ Scribed by Junji Itoh; Soo Bong Han; Michael J. Krische

Publisher
John Wiley and Sons
Year
2009
Weight
53 KB
Volume
40
Category
Article
ISSN
0931-7597

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Enantioselective Allylation, Crotylation
Enantioselective Allylation, Crotylation, and Reverse Prenylation of Substituted Isatins: Iridium-Catalyzed CC Bond-Forming Transfer Hydrogenation
✍ Junji Itoh; Soo Bong Han; Michael J. Krische 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 385 KB 👁 1 views

3-Substituted 3-hydroxy-oxindoles appear as substructures within a fascinating array of natural products, including the convulutamydines, [1a,b] maremycins, [1c,d] donaxaridines, [1e,f] dioxibrassinins, [1g,h,i] celogentin K, [1j] hydroxyglucoisatisins, [1k] and TMC-95A-D (Figure 1). [1l] Whereas ca