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ChemInform Abstract: Enantioselective 1,4-Addition Reactions of Diphenyl Phosphite to Nitroalkenes Catalyzed by an Axially Chiral Guanidine.

✍ Scribed by Masahiro Terada; Takashi Ikehara; Hitoshi Ube

Publisher
John Wiley and Sons
Year
2008
Weight
47 KB
Volume
39
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Thiourea-Catalyzed
ChemInform Abstract: Thiourea-Catalyzed Organocatalytic Enantioselective Michael Addition of Diphenyl Phosphite to Nitroalkenes.
✍ Ana Alcaine; Eugenia Marques-Lopez; Pedro Merino; Tomas Tejero; Raquel P. Herrer πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 1 views

## Abstract A variety of enantioenriched β‐nitrophosphonates (III) is readily obtained by asymmetric Michael addition of diphenylphosphite (II) to nitroolefins (I) in the presence of a bifunctional amineβ€”thiourea organocatalyst.