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ChemInform Abstract: Enantiopure Quaternary α-Trifluoromethyl-α-alkoxyaldehydes from L-Tartaric Acid Derived Ketoamides.

✍ Scribed by Jean Nonnenmacher; Fabien Massicot; Fabienne Grellepois; Charles Portella

Publisher
John Wiley and Sons
Year
2009
Weight
39 KB
Volume
40
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Highly Diastereoselective Synthesis of Quaternary α-Trifluoromethyl α-Amino Acids from Chiral Imines of Trifluoropyruvate.
✍ Qiao-Qiao Min; Chun-Yang He; Haibing Zhou; Xingang Zhang 📂 Article 📅 2011 🏛 John Wiley and Sons ⚖ 34 KB 👁 1 views

## Abstract An efficient highly diastereoselective synthesis of quaternary α‐trifluoromethyl amino acids (III) and (V) is developed via allylation of enantiopure imines of trifluoropyruvate (I).