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ChemInform Abstract: Enantiomerically Pure Isoxazolines by Stereoselective 1,3-Dipolar Cycloaddition of Silyl Nitronates.

✍ Scribed by G. GALLEY; P. G. JONES; M. PAETZEL


Book ID
112040424
Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
27
Category
Article
ISSN
0931-7597

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The cycloaddition reactions of in situ generated silyl nitronates 3 to chiral enone la or enoate l b proceed with high stereoselectivity to give enantiomericaUy pure N-silyloxyisoxazolidines 4, which can easily be transformed into A2-isuxazolines 5. Based on an X-ray analysis the major diastereomer

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v