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ChemInform Abstract: Enantioenriched Acid, Ester, and Ketone β-Phenyl Homoenolate Synthetic Equivalents from N-Boc-N-(p-methoxyphenyl)cinnamylamine.

✍ Scribed by Marna C. Whisler; Eric D. Soli; Peter Beak

Book ID
101902986
Publisher
John Wiley and Sons
Year
2001
Weight
36 KB
Volume
32
Category
Article
ISSN
0931-7597

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Enantioenriched acid, ester, and ketone
Enantioenriched acid, ester, and ketone β-phenyl homoenolate synthetic equivalents from N-Boc-N-(p-methoxyphenyl)cinnamylamine
✍ Marna C Whisler; Eric D Soli; Peter Beak 📂 Article 📅 2000 🏛 Elsevier Science 🌐 French ⚖ 64 KB

Oxidation of the b-substituted highly enantioenriched aldehydes obtained by hydrolysis of the 3,3-disubstituted enecarbamates affords enantioenriched b-substituted acids and esters. Lithiation of enantioenriched 3,3-disubstituted enecarbamates and subsequent reaction with electrophiles provides viny