ChemInform Abstract: An Enantiodivergent
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F. BRACHER; B. SCHULTE
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Article
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2010
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John Wiley and Sons
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An Enantiodivergent Synthesis of Both Enantiomers of the Macrocyclic Lactone Curvularin. -An enantiodivergent synthesis of curvularin (S)-(IX) and its enantiomer is presented based on the esterification of key intermediate (S)-(V) under either retention or inversion of the chiral center leading to