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ChemInform Abstract: Enantiocontrolled [5 + 2] Cycloaddition to η3-Pyranylmolybdenum π-Complexes. Synthesis of Substituted Oxabicyclo[3.2.1]octenes of High Enantiopurity.

✍ Scribed by Jingjun Yin; Lanny S. Liebeskind

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
30
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Chiral Allyl Cation
ChemInform Abstract: Chiral Allyl Cations in Cycloadditions to Furan: Synthesis of 2-(1′-Phenylethoxy)-8-oxabicyclo[3.2.1]oct-6-en-3-one in High Enantiomeric Purity.
✍ C. B. W. STARK; U. EGGERT; H. M. R. HOFFMANN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB

Chiral Allyl Cations in Cycloadditions to Furan: Synthesis of 2-(1'-Phenylethoxy)-8-oxabicyclo[3.2.1]oct-6-en-3-one in High Enantiomeric Purity. -The new diastereo-and enantioselective route to the title compound (III) uses chiral 1-phenylethanol as both a convenient chiral auxiliary and a protecti