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ChemInform Abstract: Enantiocontrol in the Intermolecular Cyclopropanation Reaction Catalyzed by Dirhodium(II) Complexes with ortho-Metalated Aryl Phosphine Ligands.

✍ Scribed by Mario Barberis; Pascual Lahuerta; Julia Perez-Prieto; Mercedes Sanau


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
32
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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ChemInform Abstract: Asymmetric Reaction
✍ H. ISHITANI; K. ACHIWA πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 30 KB πŸ‘ 2 views

Asymmetric Reactions Catalyzed by Chiral Metal Complexes. Part 77. Synthesis of an Axially Dissymmetric Biphenylcarboxylate Ligand, BDME, and Asymmetric Cyclopropanation of Olefins with Diazoacetate Catalyzed by Its Dirhodium(II) Complex. -The dirhodium complex of title ligand (R)-BDME serves as c