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ChemInform Abstract: Enantiocontrol in the Generation and Diastereoselective Reactions of Catalytically Generated Oxonium and Iodonium Ylides. Metal-Stabilized Ylides as Reaction Intermediates.

✍ Scribed by M. P. DOYLE; D. C. FORBES; M. M. VASBINDER; C. S. PETERSON

Publisher: John Wiley and Sons
Year: 2010
Weight: 35 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199850028

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✦ Synopsis

1998 stereochemistry stereochemistry (general, optical resolution) O 0030 50 -028 Enantiocontrol in the Generation and Diastereoselective Reactions of Catalytically Generated Oxonium and Iodonium Ylides. Metal-Stabilized Ylides as Reaction Intermediates.

-Metal-associated ylides, generated by catalytic decomposition of diazocarbonyl compounds in the presence of allyl Me ethers, are the primary product-forming intermediates in [2,3]-sigmatropic rearrangements, which occur with high enantiocontrol in the presence of chiral metal catalysts. -(DOYLE, M.

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