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ChemInform Abstract: Enantio- and Diastereocontrolled Synthesis of an Angular Triquinane Sesquiterpene (+)-Arnicenone.

✍ Scribed by Yosuke Iura; Tsutomu Sugahara; Kunio Ogasawara

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
32
Category
Article
ISSN
0931-7597

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Enantioselective Construction of Angular Triquinanes Through an Asymmetric Intramolecular Pauson-Khand Reaction. Synthesis of (+)-15-Nor-pentalenene. -It is shown for the first time that a structurally complex angular triquinane, (+)-(IX), can be obtained in a short, convergent, and enantioselectiv