ChemInform Abstract: Enamine Oxidations. Part 2. Selective Oxidative Cleavage of β,. beta. - Disubstituted Enamines Using Alumina Supported Permanganate. Synthesis of One-Carbon Dehomologated Carbonyl Compounds from Enamines.

Enamine oxidations. 2. Selective oxidati

Enamine oxidations. 2. Selective oxidative cleavage of β,β - disubstituted enamines using alumina supported permanganate. Synthesis of one-carbon dehomologated carbonyl compounds from enamines

✍ Clifford E. Harris; William Chrisman; Sally A. Bickford; Lawrence Y. Lee; Antoni 📂 Article 📅 1997 🏛 Elsevier Science 🌐 French ⚖ 202 KB

Treatment of fl, fl -disubstituted enamines with potassium permanganste suppocted on neutral alumina leads to a mild and selective oxidative cleavage reaction which produces ketones and formamides. The ketones can be isolated in high yield and purity by a simple workup procedure. The oxidizing agent