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ChemInform Abstract: Electrosynthesis of New Functionalized Difluoro Allylsilanes.

✍ Scribed by M. RAJAONAH; M. H. ROCK; J.-P. BEGUE; D. BONNET-DELPON; S. CONDON; J.-Y. NEDELEC

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

1998 organo-silicon compounds, isocyclic C derivatives organo-silicon compounds, isocyclic C derivatives S 0064

32 -219

Electrosynthesis of New Functionalized Difluoro Allylsilanes.

-The electrochemical silylation of chlorodifluoromethyl enol ethers (I) with Tms-Cl (II) affords the new functionalized difluoro allylsilanes (III), which react as difluoromethyl anion equivalents with aldehydes (IV) yielding functionalized Ξ±-difluoro alcohols (V). -(RAJAONAH, M.;

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