Regio-and Stereochemistry on the Electrophilic Trapping of Allylic Samariums Generated by Reductive Cleavage of Allylic Ethers with (C 5 Me 5 ) 2 Sm(thf )n. -The reductive cleavage of the C-O bond of allylic benzyl ethers with Sm(C 5 Me 5 ) 2 (thf) 2 leads to substituted allylic Sm complex intermed
✦ LIBER ✦
ChemInform Abstract: Electrostatic and Electrophilic Catalysis in the Reductive Cleavage of Alkyl Aryl Ethers. The Influence of Ion Pairing on the Regioselectivity.
✍ Scribed by Francisco Casado; Luisa Pisano; Maria Farriol; Iluminada Gallardo; Jordi Marquet; Giovanni Melloni
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
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ChemInform Abstract: Regio- and Stereoch
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