ChemInform Abstract: Electronic Factors in the C-Glycosidation with Silylacetylene.
β Scribed by Minoru Isobe; Rungnapha Saeeng; Rena Nishizawa; Masato Konobe; Toshio Nishikawa
- Book ID
- 101888763
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Electronic Factors in the C-Glycosidation with Silylacetylene.
-The title reaction is found to depend on the protecting group of the silylacetylenes, e.g. (II). On the basis of mixing experiments with glucal and galactal derivatives like (I) and (IV), other factors to control the reactivity are investigated. -(ISOBE, MINORU; SAEENG, RUNGNAPHA; NISHIZAWA,
π SIMILAR VOLUMES
Double Stereodifferentiation in the Lewis Acid Promoted C-Glycosidation of Activated Glycals with Chiral (E)-Crotylsilanes. -It is shown that the pairwise combination of the glycals (I) and (V) with the chiral silanes (II) affords high levels of selectivity resulting from the existence of strong st
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