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ChemInform Abstract: Electron Transfer Initiated Free Radical Additions of Perfluoroalkyl Iodides and Diiodides to Alkenes.

✍ Scribed by J. O. METZGER; R. MAHLER; A. SCHMIDT

Book ID
112037561
Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
27
Category
Article
ISSN
0931-7597

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Electron Transfer Initiated Free Radical
Electron Transfer Initiated Free Radical Additions of Perfluoroalkyl Iodides and Diiodides to Alkenes
✍ Metzger, JΓΌRgen O. ;Mahler, Ralf ;Schmidt, Andreas πŸ“‚ Article πŸ“… 2006 πŸ› John Wiley and Sons 🌐 English βš– 393 KB

## Abstract Perfluoroalkyl iodides were added in very good yields to 1,2‐dialkyl substituted double bonds of e.g. petroselinic acid initiated by lead/copper(II) acetate in methanol and by copper without solvent, respectively. Using the new initiator system lead/copper(II) acetate, we also obtained