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ChemInform Abstract: Electrochemistry of C82: Relationship to Metallofullerene Electrochemistry.

✍ Scribed by P. B. BURBANK; J. R. GIBSON; H. C. DORN; M. R. ANDERSON

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Electrochemistry of C82: Relationship to Metallofullerene Electrochemistry.

-Square-wave voltammograms obtained in pyridine solution for C82 indicate reduction in four one-electron steps prior to the onset of electrolyte decomposition. Comparison with literature data for the endohedral complexes La C82 and Y C82 allows interpretation of the electrochemistry of metallofullerenes in terms of the electronic structure of the fullerene cage. The relative easy reduction and oxidation of La C82 and Y C82 seems to be related to the presence of the third electron given up by La and Y. For this electron no significant contribution to the aromatic Ο€ stabilization of the fullerene is assumed. -(BURBANK,

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