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ChemInform Abstract: Electrochemically Lithiated Vanadium Oxide, Li3V6O13.

✍ Scribed by OE. BERGSTROEM; T. GUSTAFSSON; J. O. THOMAS

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

The title compound is prepared by electrochemical lithiation (2.45 eV vs. Li/Li + ) of single crystals of V 6 O 13 grown by chemical vapor transport with TeCl 4 as transport agent. Li 3 V 6 O 13 crystallizes in the monoclinic space group C2/m with Z = 2. The structure comprises single and double layers of VO 6 octahedra stacked in the c-direction. Lithiation results in a 6.5% expansion along the b-axis with respect to V 6 O 13 . The Li atoms are located at two crystallographically independent sites. -(BERGSTROEM, OE.; GUSTAFSSON, T.; THOMAS,

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