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ChemInform Abstract: Elaboration of a Novel Type of Interglycosidic Linkage: Syntheses of Disulfide Disaccharides.

✍ Scribed by Laszlo Szilagyi; Tuende-Zita Illyes; Pal Herczegh

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
32
Category
Article
ISSN
0931-7597

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Elaboration of a novel type of interglyc
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Asymmetric non-reducing disaccharides containing an interglycosidic disulfide linkage were synthesised under mild conditions through reaction of tetraacetyl-b-D-glucopyranosyl methanethiolsulfonate with O-acetylated 1-thio-aldopyranoses. The preferred conformation around the S S bond is close to tha

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Versatile Novel Syntheses of Imidazoles. -Novel methods for the synthesis of imidazoles possessing substitution patterns difficult to obtain by other routes are presented.