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ChemInform Abstract: Efficient Synthesis and NMR Data of N- or B-Substituted Borazines.

✍ Scribed by Eric Framery; Michel Vaultier

Publisher: John Wiley and Sons
Year: 2010
Weight: 27 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200028171

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The thermolysis of borane-primary amine complexes RNH 2 .BH 3 was reexamined. Excellent yields of N-substituted borazines were obtained at 200ЊC, when R is an alkyl group, and at 120ЊC for R ‫ס‬ Ph. B-alkyl, vinyl, and alkynyl borazines were easily prepared in good to excellent yields by ammonolysis

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