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ChemInform Abstract: Efficient Methodology for the Construction of Substituted Spiroketals. Model Studies Towards the Synthesis of the Eastern Spiroketal Subunit of Okadaic Acid.

✍ Scribed by I. E. MARKO; F. CHELLE

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199732110

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A Vinylogous Urethane Approach Towards the Synthesis of Okadaic Acid. Construction of the C 9 -C 18 Fragment. Part 2. -In the approach towards the C 9 to C 18 fragment (XI), a diastereo-and enantioselective acylation-reduction sequence of a vinylogous urethane lactone silylketene acetal sets the in