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ChemInform Abstract: Efficient Hydrogenation of Biomass-Derived Cyclic Di-Esters to 1,2-Diols.

โœ Scribed by Ekambaram Balaraman; Eran Fogler; David Milstein

Book ID
112045039
Publisher
John Wiley and Sons
Year
2012
Weight
27 KB
Volume
43
Category
Article
ISSN
0931-7597

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Enantiopure Derivatives of 1,1,2-Triphenylethane-1,2-diol by Unusual Ring Opening of Its Cyclic Sulfite. -Reaction of the diastereomeric mixture (II) with the alcohols (III) or the diols (V) leads to the formation of the enantiomerically pure ethers via an SN1-type ring cleavage. Treatment of (II)