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ChemInform Abstract: Efficient Double Bond Migration of Allylbenzenes Catalyzed by Pd(OAc)2—HFIP System with Unique Substituent Effect.

✍ Scribed by Nagatoshi Nishiwaki; Ryuichiro Kamimura; Kimihiro Shono; Toshihiko Kawakami; Katsuhisa Nakayama; Kohei Nishino; Takayuki Nakayama; Keisuke Takahashi; Aki Nakamura; Takahiro Hosokawa

Publisher: John Wiley and Sons
Year: 2010
Weight: 39 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201040057

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✦ Synopsis

Abstract

The system promotes the double bond isomerization under mild conditions and generally within a short time to give the (E) isomers nearly exclusively.

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