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ChemInform Abstract: Efficient Dehydrocyanation of Hindered 1-Substituted Olefins.

โœ Scribed by O. Temmem; D. Uguen; A. De Cian; N. Gruber

Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
33
Category
Article
ISSN
0931-7597

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Synthesis of Hindered and Functionalized 1-CF3 Substituted Olefins via a Carbolithiation-Elimination-Metalation Cascade. -Trisubstituted fluoroalkenes of type (III) are obtained stereoselectively. They react further with organolithium reagents and undergo vinyl metalation to give, after trapping wi