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ChemInform Abstract: Efficient Conversion of Silyl Ethers to Thiocyanates with Ph3P(SCN)2.

โœ Scribed by N. Iranpoor; H. Firouzabadi; H. Shaterian


Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
31
Category
Article
ISSN
0931-7597

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ChemInform Abstract: An Efficient and St
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An Efficient and Stereoselective Conversion of Lactones to Substituted Cyclic Ethers. -Cerium(III) chloride assisted addition of Grignard reagents to lactones and following BF 3 โ€ขOEt 2 mediated deoxygenation of the resulting hemiketals [cf. (III)] with triethylsilane provides a general route to cycl