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ChemInform Abstract: Efficient C—H Activation of Alkylbenzenes and Methylcyclohexenes to Benzyl Esters by Pd(OAc)2/Sn(OAc)2 Catalyst System.

✍ Scribed by T. OHISHI; Y. TANAKA; J. YAMADA; H. TAGO; M. TANAKA; M. YAMASHITA


Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
29
Category
Article
ISSN
0931-7597

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Efficient C–H activation of alkylbenzene
✍ Takahiro Ohishi; Yumiko Tanaka; Junko Yamada; Hiromi Tago; Mutsumi Tanaka; Masak 📂 Article 📅 1997 🏛 John Wiley and Sons 🌐 English ⚖ 164 KB

Selective activation of the side-chain C-H bond of alkylbenzenes and methylcyclohexenes is achieved by a Pd(OAc) 2 /Sn(OAc) 2 catalyst system. Under an oxygen atmosphere, various benzyl esters were obtained from the substrates and carboxylic anhydrides. The esters were obtained in more than 100% yie