Although the acetylenic carbon atoms in 2 are closer together than those in 1, only the latter undergoes Bergman cyclization. In contrast, in analogous enediynes without an annelated cyclohexane ring a change in the hybridization of the bridging carbon atom from sp to sp leads to a dramatic increase
β¦ LIBER β¦
ChemInform Abstract: Effects of Propargylic Substitution and Anellation on the Cycloaromatization of a Bicyclo[7.3.1] Enediyne.
β Scribed by David K. Moss; John D. Spence; Michael H. Nantz
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 25 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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