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ChemInform Abstract: Effect of the Pressure on Organic Reactions

✍ Scribed by F.-G. KLAERNER; M. K. DIEDRICH; A. E. WIGGER


Publisher
John Wiley and Sons
Year
2010
Weight
24 KB
Volume
28
Category
Article
ISSN
0931-7597

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The activation and reaction volumes (βˆ†V /βˆ†V) were showing negative volumes of activation (βˆ†V Ο½ 0) whereas the others are slightly retarded (βˆ†V ΟΎ 0). From the analysis determined for the retro Diels-Alder reactions of the parent dihydrobarrelene 1a, its 2-cyano derivative 1b, the exo and of the volum