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ChemInform Abstract: Effect of the Grignard Reagent on the X→Csp Migration of the MR3 Group in HCCCH2XMR3 Compounds.

✍ Scribed by V. V. Novokshonov; A. S. Medvedeva; A. V. Mareev

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
33
Category
Article
ISSN
0931-7597

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ChemInform Abstract: The Stereochemistry
ChemInform Abstract: The Stereochemistry of the Grignard -Ortho Ester Reaction Revisited: Regioselective Endocyclic Cleavage in the Reaction of Grignard Reagents with cis-2-Methoxy-4-methyl-1,3-dioxane.
✍ W. F. BAILEY; A. A. CROTEAU; A. D. RIVERA 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 29 KB 👁 2 views

The Stereochemistry of the Grignard -Ortho Ester Reaction Revisited: Regioselective Endocyclic Cleavage in the Reaction of Grignard Reagents with cis-2-Methoxy-4-methyl-1,3-dioxane. -cis-Dioxane (Ia) selectively reacts with Grignard reagents (cf. (II)) via rupture of the less congested C(2)-O(1) bo