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ChemInform Abstract: Effect of Aryl Substituents on Intramolecular Cyclization of 2,2′-Biphenoquinones.

✍ Scribed by Naoto Hayashi; Akifumi Kanda; Taku Kamoto; Hiroyuki Higuchi; Takeyuki Akita

Publisher
John Wiley and Sons
Year
2009
Weight
30 KB
Volume
40
Category
Article
ISSN
0931-7597

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ChemInform Abstract: Remote Substituent
ChemInform Abstract: Remote Substituent Effects on the Enantiomeric Excess of Intramolecular Asymmetric Palladium-Catalyzed Polyene Cyclizations.
✍ Stephen Y. W. Lau; Brian A. Keay 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB 👁 2 views

Remote Substituent Effects on the Enantiomeric Excess of Intramolecular Asymmetric Palladium-Catalyzed Polyene Cyclizations. -Remote substituents show a strong influence on the enantioselectivity of the title reactions. Excellent enantioselectivity is obtained by cyclization of the O-methyl triflate