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ChemInform Abstract: (E)-Bis-1,2-(tributylstannyl)ethylene as a Staple in a Synthetic Approach to Taxol.

✍ Scribed by F. DALALOGE; J. PRUNET; A. PANCRAZI; J.-Y. LALLEMAND

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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(E)-Bis-1,2-(tributylstannyl)ethylene as
(E)-Bis-1,2-(tributylstannyl)ethylene as a staple in a synthetic approach to taxol
✍ Francette Delaloge; JoΓ«lle Prunet; Ange Pancrazi; Jean-Yves Lallemand πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 287 KB

An approach of taxol synthesis based on the use of (E)-bis-l,2-(tributylstannyl)ethylene 6 as a readily available two-carbon 1,2-1ink between A and C-ring is described, The conjugate addition of a mixed higher-order stannylvinyl cyanocuprate derived from 6 on chkal cyclobexenone $ is completely ster