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ChemInform Abstract: Dynamics of Ionization Reactions of β-Substituted Radicals. Substituent and Solvent Effects.

✍ Scribed by F. L. COZENS; M. O'NEILL; R. BOGDANOVA; N. SCHEPP

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Dynamics of Ionization Reactions of β-Substituted Radicals. Substituent and Solvent Effects.

-The primary mode of decay of the radicals (I) and (II), generated by laser photolysis, under ionizing conditions is heterolytic cleavage of the β-chloro or β-bromo substituent to generate the corresponding radical cations. Kinetic investigations reveal that the rate constants for and the yield of the heterolysis reaction are dependent on both the solvent ionizing ability and radical structure. -(COZENS, F.

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