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ChemInform Abstract: Distannoxane-Catalyzed Highly Selective Acylation of Alcohols.

โœ Scribed by A. ORITA; A. MITSUTOME; J. OTERA


Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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Trinuclear tin salicylaldoximate cluster
โœ Carlos Camacho-Camacho; Monique Biesemans; Ingrid Verbruggen; Rudolph Willem ๐Ÿ“‚ Article ๐Ÿ“… 2005 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 93 KB

The reactivity and catalytic potential of the tin salicylaldoximate cluster [(Me 2 Sn) 2 (Me 2 SnO)(OCH 3 ) (HONZO)(ONZO)] (1), with HONZOH = o-HON CH-C 6 H 4 OH, on the acylation reaction of various alcohols with ethyl acetate is reported. The catalyst is active toward primary and unhindered second