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ChemInform Abstract: Direct Synthesis of trans-1,4-Diacetoxycyclohexa-2,5-diene by Electrochemical Reduction of r-1,t-4-Diacetoxy-t-2,c-3-dibromocyclohex-5-ene.

✍ Scribed by L. KELEBEKLI; UE. DEMIR; Y. KARA

Publisher: John Wiley and Sons
Year: 2010
Weight: 28 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199809077

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✦ Synopsis

Direct Synthesis of trans-1,4-Diacetoxycyclohexa-2,5-diene by Electrochemical Reduction of r-1,t-4-Diacetoxy-t-2,c-3-dibromocyclohex-5-ene.

-Electrochemical reduction of diacetoxy-dibromo-cyclohexene (I) gives only cyclohexadiene (II), while the commonly used Zn-reduction gives a mixture containing (II) and acetoxybenzene (III) or (III) alone. -

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