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ChemInform Abstract: Direct Synthesis of Quinazolines Through Copper-Catalyzed Reaction of Aniline-Derived Benzamidines.

โœ Scribed by Yusuke Ohta; Yusuke Tokimizu; Shinya Oishi; Nobutaka Fujii; Hiroaki Ohno

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
41
Category
Article
ISSN
0931-7597

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โœฆ Synopsis

Abstract

Alkynylation of the title compounds with the iodoxolone derivative (II) is followed by cyclization to produce the biologically interesting quinazoline skeleton (III) in moderate yield.

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ChemInform Abstract: Copper-Catalyzed Di
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## Abstract By use of a Cu(II)โ€”Cu(0) catalytic system, nitrosoarenes and alkynes undergo an annulation/deoxygenation reaction to give the desired indoles.