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ChemInform Abstract: Direct Synthesis of Metal-Complexed Aromatic Amino Acid Derivatives by Palladium-Catalyzed Coupling Processes.

✍ Scribed by R. F. W. JACKSON; D. TURNER; M. H. BLOCK

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199707093

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✦ Synopsis

Direct Synthesis of Metal-Complexed Aromatic Amino Acid Derivatives by Palladium-Catalyzed Coupling Processes.

-The Pd(0)-catalyzed coupling reaction of chromium complexes (I) with the serinederived organozinc reagent (II) and subsequent decomplexation of the resulting (III) provides a useful preparation of phenylalanine derivatives (IV). A similar reaction using the diiodoferrocene provides a mixture of the mono-and bisproduct (VI) and (VII) depending on the educts ratio. -(JACKSON, R. F.

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