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ChemInform Abstract: Direct Ruthenium-Catalyzed C—C Coupling of Ethanol: Diene Hydro-hydroxyethylation to Form All-Carbon Quaternary Centers.

✍ Scribed by Hoon Han; Michael J. Krische

Publisher: John Wiley and Sons
Year: 2010
Weight: 55 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201045061

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✦ Synopsis

Abstract

anti‐configured neopentyl homoallylic alcohols with an all‐carbon quaternary center are prepared as the major products with moderate to high diastereoselectivity starting from dienes (I) and ethanol (II) or acetaldehyde (V).

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