A novel and straightforward method to construct 1H-benzo [d]imidazole was developed b means of Pd II -catalyzed intramolecular CÀH activation starting from readily available N-phenylbenzimidamide. The detailed mechanism studies indicated that a palladacycle monomer or dimer is the key intermediate f
ChemInform Abstract: Direct Imidation of Construct 1H-Benzo[d]imidazole Through Pd(II)-Catalyzed C—H Activation Promoted by Thiourea.
✍ Scribed by Qing Xiao; Wen-Hua Wang; Gang Liu; Fan-Ke Meng; Jia-Hua Chen; Zhen Yang; Zhang-Jie Shi
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 43 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option.
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## Abstract Intramolecular cyclization of tertiary phenylethanol derivatives, e.g. (I), (III) or (V), proceeds smoothly in the presence of Pd(II) catalyst and Ph‐I(O‐Ac)~2~ to give dihydrobenzofuran derivatives in good yields.
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v