ChemInform Abstract: Direct Asymmetric Aldol Reactions in Water with a β-Aminosulfonamide Organocatalyst.
✍ Scribed by Tsuyoshi Miura; Mariko Ina; Kie Imai; Kosuke Nakashima; Yumi Yasaku; Naka Koyata; Yasuoki Murakami; Nobuyuki Imai; Norihiro Tada; Akichika Itoh
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 32 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
Abstract
Best results are achieved performing the reaction in the presence of water instead of brine to afford the corresponding aldol products with anti‐selectivity.
📜 SIMILAR VOLUMES
## Abstract SUA efficiently catalyzes the reaction between aldehydes and cyclic ketones to yield anti‐aldol products with high enantioselectivity.
## Abstract The new fluorous sulfonamide PFSA promotes effectively the aldol reaction at room temperature and in a shorter time compared to the diamine precursor.