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ChemInform Abstract: Diphenylphosphinoylethylidene (DPE) Acetals: An Alternative Protective Strategy in Glycochemistry.

✍ Scribed by Leonardo Pellizzaro; Arnaud Tatibouet; Fabrizio Fabris; Patrick Rollin; Ottorino De Lucchi

Publisher
John Wiley and Sons
Year
2009
Weight
47 KB
Volume
40
Category
Article
ISSN
0931-7597

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Diphenylphosphinoylethylidene (DPE) acet
Diphenylphosphinoylethylidene (DPE) acetals: an alternative protective strategy in glycochemistry
✍ Leonardo Pellizzaro; Arnaud TatibouΓ«t; Fabrizio Fabris; Patrick Rollin; Ottorino πŸ“‚ Article πŸ“… 2009 πŸ› Elsevier Science 🌐 French βš– 187 KB

b s t r a c t Diphenylphoshinoylethyne reacts with diols under basic conditions to produce cycloacetalic phosphine oxides. The reaction appears to be general and particularly effective with carbohydrate derivatives. The 2-(diphenylphoshinoyl)ethylidene (DPE) acetals produced are stable in acidic med

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✍ Antonella Leggio; Angelo Liguori; Anna Napoli; Carlo Siciliano; Giovanni Sindona πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 28 KB πŸ‘ 2 views

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