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ChemInform Abstract: Diphenylparabanic Acid as a Synthon for the Synthesis of α-Diketones and α-Ketocarboxylic Acids.

✍ Scribed by Nobuko Watanabe; Mitsutaka Hamano; Shota Todaka; Takahiro Asaeda; Hisako K. Ijuin; Masakatsu Matsumoto

Book ID
112044534
Publisher
John Wiley and Sons
Year
2012
Weight
49 KB
Volume
43
Category
Article
ISSN
0931-7597

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Featuring the Use of a Dihydropyranone as a 1,5-Diketone Synthon. -A short synthesis of the antifungally active sesquiterpene α-herbertenol (VII) is described. Key steps are the addition of an aryllithium reagent to dihydropyranone (II), which is used as 1,5-diketone synthon, and a titanium promote