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ChemInform Abstract: Dimethyldioxirane Oxidation of Exocyclic (E,E)-Cinnamylideneketones.

✍ Scribed by Albert Levai; Artur M. S. Silva; Clementina M. M. Santos; Jose A. S. Cavaleiro; Jozsef Jeko

Publisher
John Wiley and Sons
Year
2009
Weight
43 KB
Volume
40
Category
Article
ISSN
0931-7597

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Oxidation of Isothiocyanates to Isocyanates Using Dimethyldioxirane; Relevance to Biological Activity of Isothiocyanates. -Oxidation of both alkyl and aryl isothiocyanates with dimethyldioxirane affords efficiently the corresponding isocyanates (II), which are trapped with iPrNH 2 to furnish the ur