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ChemInform Abstract: Dimerization of β-Iodo-α,β-unsaturated Enones by Samarium(II) Iodide.

✍ Scribed by H.-Y. KANG; M. S. PARK; B.-N. PARK; H. Y. KOH

Publisher
John Wiley and Sons
Year
2010
Weight
34 KB
Volume
29
Category
Article
ISSN
0931-7597

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Hydrodimerization of Cyclic α,β Unsaturated Ketones Promoted by Samarium Iodide. -The intermolecular coupling of cyclic unsaturated ketones by SmI 2 /THF and SmI 2 /HMPA/THF systems, resp., affords symmetrical hydrodimers in a short reaction time and in good yields. The use of HMPA improves the yie