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ChemInform Abstract: Diethyl Acetylaminoallylmalonate in Reaction with Methyl Diazoacetate.

✍ Scribed by N. A. Anisimova; G. A. Berkova; L. Deiko

Publisher
John Wiley and Sons
Year
2010
Weight
27 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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Reactions of Ethyl Diazoacetate with Thioketones. -The 1,3-dipolar cycloaddition of ethyl diazoacetate (II) with thioketones is investigated. The most reactive dipolarophiles (I) give 1,3-dithiolanes, e.g. (III), (V), (VI) and (VIII). Sterically crowded thioketones (IX) and (XII) as well as the less