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ChemInform Abstract: Diepoxy[18]annulenes(10.0): (Z,E,Z,E,Z)-Diepoxy[18]annulene(10.0) — A Highly Dynamic Annulene.

✍ Scribed by Gottfied Maerkl; Thomas Knott; Peter Kreitmeier; Thomas Burgmeiter; Fritz Kastner

Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

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Diepoxy[18]annulene(10.0) : (Z,E,Z,E,Z)-
Diepoxy[18]annulene(10.0) : (Z,E,Z,E,Z)-Diepoxy[18]annulen(10.0) – ein hochdynamisches Annulen
✍ Gottfried Märkl; Thomas Knott; Peter Kreitmeier; Thomas Burgemeister; Fritz Kast 📂 Article 📅 2000 🏛 John Wiley and Sons 🌐 German ⚖ 213 KB

Diepoxy [18]annulenes(10.0): (Z,E,Z,E,Z)-Diepoxy [18]annulene(10.0) ± a Highly Dynamic Annulene The McMurry reaction of (all-E)-5,5'-([2,2'-bifuran]-5,5'-diyl)bis[penta-2,4-dienal] (13) only occurs intramolecularly to give a mixture of the diepoxy[18]annulenes(10.0) 6 and 7. Tetraepoxy[36]annulene(