tert-Butylphosphaethyne (2) undergoes a Diels-Alder in 4, complexation occurs exclusively at its phosphaalkene phosphorus atom. The reactivity of 2 towards the four reaction with the 1,3,2-diazaphosphinine 1 at room temperature to furnish the diazadiphosphabarrelene 3. In the functionally substitute
✦ LIBER ✦
ChemInform Abstract: Diels—Alder Reactions of tert-Butylphosphaethyne with 1,3,2-Diaza- and 1,2-Azaphosphinines.
✍ Scribed by N. AVARVARI; L. RICARD; F. MATHEY; P. LE FLOCH; O. LOEBER; M. REGITZ
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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