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ChemInform Abstract: Diels—Alder Reactions of Enantiopure [(1S)-Isoborneol-10-sulfinyl]- and [(1S-exo)-2-Bornylsulfinyl]vinylcyclohexenes with Maleimides.

✍ Scribed by Maria C. Aversa; Anna Barattucci; Paola Bonaccorsi; Placido Giannetto; Francesco Nicolo; Simona Rizzo


Publisher
John Wiley and Sons
Year
2010
Weight
39 KB
Volume
31
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

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✍ P. GOSSELIN; E. BONFAND; C. MAIGNAN 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB

Application of the Stereoselective Diels-Alder Reaction of Enantiopure 2-Sulfinyl Dienes: Synthesis of (-)-(1S,5R)-Karahana Ether. -The natural karahana ether (VII) is synthesized for the first time by application of sulfinyl derivative (I) as chiral auxiliary in asymmetric Diels-Alder reaction and