ChemInform Abstract: Diels—Alder and Michael Addition Reactions of Indoles with Masked o-Benzoquinones: Synthesis of Highly Functionalized Hydrocarbazoles and 3-Arylindoles.
✍ Scribed by Ming-Fang Hsieh; Polisetti Dharma Rao; Chun-Chen Liao
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 32 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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✦ Synopsis
1999 indole derivatives, isoindole derivatives indole derivatives, isoindole derivatives R 0140 46 -131 Diels-Alder and Michael Addition Reactions of Indoles with Masked o-Benzoquinones: Synthesis of Highly Functionalized Hydrocarbazoles and 3-Arylindoles. -Depending on the reaction temperature and the substitution pattern, indoles undergo Diels-Alder or Michael addition to masked o-benzoquinones, generated from phenols (I), to furnish cycloadducts such as (IV) and (VII) or aromatized Michael adducts [cf. (V)]. -(HSIEH,
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