ChemInform Abstract: Diels-Alder Reaction of Deactivated Dienes with Electron-Poor Dienophiles.
✍ Scribed by S. CHATTOPADHYAY; D. MAHADANI; D. P. ACHARYA; N. GHOSHAL; B. ACHARI
- Book ID
- 112036203
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 28 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
Diels-Alder Reactions of Diaryl Thioketones with Dienophiles. -The reaction with the acetylenes (II) gives rearomatized adducts of type (III), while with (E)-cyclooctene the initial nonaromatic products (V) can be isolated.
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## Abstract o‐Benzoquinone monoketals, generated in situ by oxidation of o‐methoxyphenols (I) in the presence of methanol, undergo Diels—Alder reaction with olefins (III) and dihydrofuran to give the endo adducts (IV) and (VI) selectively.