ChemInform Abstract: Diastereoselectivity in the Reduction of Acyclic Carbonyl Compounds with Diisopropoxytitanium(III) Tetrahydroborate.
โ Scribed by K. S. Ravikumar; Surajit Sinha; S. Chandrasekaran
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 33 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
High 1,6-Diastereoselectivity in the Hydride Reduction of an Acyclic Ketone Substrate via Bicyclic Chelation Control. -Reduction of the .epsilon.-hydroxyketone (I) with (R)-Alpine hydride provides the corresponding diol (II) with strong preponderance of the anti-diastereomer. The high degree of ste
Practical Reduction of Carbonyl Compounds with NaBH 4 and Silica Gel in an Aprotic Solvent. -The high-yielding reduction of 20 carbonyl compounds like (I) and (III) is described using a combination of NaBH 4 and SiO 2 under mild conditions. -(YAKABE, SHINGETAKA; HIRANO,