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ChemInform Abstract: Diastereoselectivity in the Addition of Organocerium Reagents to 4- and 5-Oxazolidonecarbaldehydes: Synthesis of syn- and anti-Alcohols.

✍ Scribed by A. G. H. WEE; F. TANG

Book ID
112042043
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
27
Category
Article
ISSN
0931-7597

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Chiral non-racemic 4-and 5-oxazolidonecarbaldehydes, typified by 2 and 7, react highly diastereoselectively with organocerium reagents to give moderate to good yields of syn-and anti-alcohols, respectively. Rationalizations for the observed diastereoselectivities are presented. The synthetic potenti

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